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Comb and Bottlebrush Graft Copolymers in a Melt

May 16, 2019

Heyi Liang, Zilu Wang, Sergei S. Sheiko, and Andrey V. Dobrynin We have studied properties of comb-like and bottlebrush-like graft copolymers made of chemically different backbones and side chains in a melt. A diagram of states for this class of … Read more

Strained Bottlebrushes in Super-Soft Physical Networks

April 23, 2019

Charles Clair, Abdelaziz Lallam, Martin Rosenthal, Michael Sztucki, Mohammad Vatankhah-Varnosfaderani, Andrew N. Keith, Yidan Cong, Heyi Liang, Andrey V. Dobrynin, Sergei S. Sheiko, and Dimitri A. Ivanov ABA triblock copolymers composed of a poly(dimethylsiloxane) (PDMS) bottlebrush central block and linear … Read more

Encoding tissue mechanics in silicone

May 30, 2018

Sergei S. Sheiko, Matthew H. Everhart, Andrey V. Dobrynin, Mohammad Vatankhah-Varnosfaderani By controlling polymer-network architecture, we outline a roadmap for the creation of tissue-like materials to extend the performance of soft robots to harsh environments. Read Article

Supersoft and Hyperelastic Polymer Networks with Brushlike Strands

January 11, 2018

Heyi Liang, Sergei S. Sheiko, and Andrey V. Dobrynin Using a combination of the scaling analysis and molecular dynamics simulations, we study relationship between mechanical properties of networks of graft polymers and their molecular architecture. The elastic response of such … Read more

Mimicking biological stress–strain behaviour with synthetic elastomers

September 4, 2017

Mohammad Vatankhah-Varnosfaderani, William F. M. Daniel, Matthew H. Everhart, Ashish A. Pandya, Heyi Liang, Krzysztof Matyjaszewski, Andrey V. Dobrynin & Sergei S. Sheiko Despite the versatility of synthetic chemistry, certain combinations of mechanical softness, strength, and toughness can be difficult … Read more